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CHE 101
GENERAL CHEMISTRY I
Lecture Outlines |
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I: INTRODUCTION
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The Scientific Method |
Definitions |
States of Matter |
Exponential Notation |
Conversion Factors |
S.I. Units |
Area and Volume |
Density |
Temperature |
Significant Figures |
Dimensional Analysis |
Percent Composition |
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II: THE ATOM
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Early Atomic Theory |
Electricity and Magnetism |
Experiments Leading to Modern Atomic Theory |
Elements/Particles/Atomic Number |
Isotopes |
Percent Abundance |
Atomic Weights |
An Introduction to the Periodic Chart |
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III: COMPOUNDS
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The Mole Concept |
Example Mole Calculations |
Writing Chemical Formulas |
More About Ions |
Guidelines for Determining the Charge on an Ion |
Ionic Compounds |
Molar Mass Percent Composition |
Two Different Types of Chemical Formulas |
Combustion Analysis |
Rules for Assigning Oxidation Numbers |
Chemical Nomenclature |
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IV: CHEMICAL REACTIONS
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Chemical Reactions |
Balancing Chemical Equations |
Stoichiometry |
The Limiting Reagent |
A Systematic Three-Step Procedure to Determine the L.R. |
Percent Yield |
More Limiting Reagent Examples |
Other Types of Reactions |
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V: AQUEOUS REACTIONS
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Reactions in Aqueous Solution |
Solute Concentrations: Molarity |
Preparing Solutions by Dilution |
Stoichiometry of Reactions in Solution |
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VI: GASES
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Physical Behavior of Gases |
Liquid Pressure |
The Barometer |
The Manometer |
Boyle's Law |
The Two-State Boyle's |
Law Charles's or Gay-Lussac's Law |
The Two-State Charles's Law |
Avogadro's Law |
Standard Temperature and Pressure (STP) |
The Ideal Gas Law |
The Two-State Ideal Gas Law |
Molar Mass-Ideal Gas Relationship |
Law of Combining Volumes |
Dalton's Law of Partial Pressures |
Mole Fraction |
Model for the Kinetic Molecular Theory of Gases |
The Speed of Gas Molecules |
Distribution of Molecular Speeds |
Effusion of Gases |
Real Gases |
The van der Waals Model of Real Gases |
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VII: THERMOCHEMISTRY
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Definitions |
Joule's Mechanical Equivalent of Heat Experiment |
Units of Energy |
Sign Conventions |
Endothermic/Exothermic Reactions |
Expansion Work Against a Constant External Pressure |
An Equation for Expansion Work |
Heat Capacity |
Specific Heat |
Experimental Determination of Specific Heat |
The Fundamental Equation of Calorimetry |
The "Coffee Cup" Calorimeter |
The Bomb Calorimeter |
The First Law of Thermodynamics |
State Properties |
An Equation for the Change in Enthalpy |
vs. |
What is Enthalpy? |
Rules of Thermochemistry |
Values of with Special Names |
Standard Conditions |
Standard Molar Enthalpies of Formation |
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VIII: INTRODUCTION TO QUANTUM THEORY
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Electromagnetic Radiation |
The Particle Nature of Light |
Atomic Line Spectra |
The Bohr Model of the Atom |
The Bohr Model Explains the Hydrogen Atom Spectrum |
Wave-Particle Duality |
The Heisenberg Uncertainty Principle |
Wave Mechanics |
The Probability Function |
Quantum Numbers and Orbitals |
The Principal Quantum Number |
The Orbital Angular Momentum Quantum Number |
The Magnetic Quantum Number |
The s Orbitals |
The p Orbitals |
The d Orbitals |
Radial Functions and Probability Plots |
The Electron Spin |
Multielectron Atoms |
The Pauli Exclusion Principle |
Energy Ordering for Multi-electron Atoms |
Electron Configurations |
The Structure of the Periodic Table |
Orbital Diagrams |
Hund's Rule |
Magnetic Properties |
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IX: PERIODICITY
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History of the Periodic Table |
Atomic Radius |
Shielding |
Ionic Radius |
Ionization Energy |
Electron Affinity |
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X: CHEMICAL BONDING
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Types of Chemical Bonds |
The Covalent Bond |
The Octet Rule |
Lewis Dot Structures |
Rules for Determining Lewis Dot Structures |
Resonance |
Electronegativity |
Polar Covalent Bonds |
Dipole Moments |
Oxidation Numbers Revisited |
Formal Charges |
Exceptions to the Octet Rule |
Molecular Geometry |
Valence Shell Electron Pair Repulsion (VSEPR) Theory |
The Effect of Unshared Pairs on Molecular Geometry |
Bond Energies |
Using Bond Energies to Estimate
for a Reaction |
The Valence Bond Model |
Bond Number and Geometry as Predicted by Valence Bond Theory |
Hybridization |
Multiple Bonds |
An Introduction to Molecular Orbital Theory |
Molecular Orbitals Formed by p Orbitals |
MO Diagrams |
Bond Order |
MO Electron Configurations |
On Orbitals and Bonding Theories |
Delocalized Electrons |